张召阳

职称：副教授

性别：男

职务：

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电子邮箱：zy_zhang@xtu.edu.cn

工作学习经历

主讲课程

《生物化学》

研究方向 

致力于光功能分子（特别是偶氮类光开关分子）的结构创新、性质优化与功能应用，主要包括：

1. 从结构设计出发，开发新（奇）结构的偶氮分子，拓展偶氮光开关的分子多样性；

2. 探究偶氮分子的结构−性质关系，优化光开关性能，克服传统光开关分子的性质缺陷；

3. 多领域交叉，探索光开关反应所触发的新颖物理化学现象及其潜在应用，例如：光化学相变现象及其在能量存储中的应用；

4. 构建光响应的智能分子材料与器件，为新材料、新技术的发展进步提供解决方案。

（个人感言: 好奇心与洞察力是科研创新的两架马车）

主要学术成果 

学术论文(*为通讯作者，^†为共同第一作者)：

29. Yixin He, Tongtong Dang, Andrew G. Leach*, Zhao-Yang Zhang, Tao Li*. Photoswitchable Azobispyrazole Crystals Achieving Near-Quantitative Crystalline-State Bidirectional E ⇆ Z Conversions. J. Am. Chem. Soc. 2024, 146, 29237–29244.

28. Tongtong Dang, Zhao-Yang Zhang*, Tao Li*. Visible-Light-Activated Heteroaryl Azoswitches: Toward a More Colorful Future. J. Am. Chem. Soc. 2024, 146, 19609−19620.

27. Dongfang Dong^†, Zhao-Yang Zhang^†, Tongtong Dang, Tao Li*. Bis-azopyrazole Photoswitches for Efficient Solar Light Harvesting. Angew. Chem. Int. Ed. 2024, 63, e202407186.

26. Zhao-Yang Zhang, Dongfang Dong, Tom Bösking, Tongtong Dang, Chunhao Liu, Wenjin Sun, Mingchen Xie, Stefan Hecht*, Tao Li*. Solar Azo-Switches for Effective E→Z Photoisomerization by Sunlight. Angew. Chem. Int. Ed.2024, 63, e202404528.

25. Huchao Li^†, Zhichun Shangguan^†, Tao Li*, Zhao-Yang Zhang, Deyang Ji*, Wenping Hu. Arylazopyrazole-Modulated Stable Dual-Mode Phototransistors. Sci. Adv. 2024, 10, eado2329.

24. Wenjin Sun, Zhichun Shangguan, Xu Zhang, Tongtong Dang, Zhao-Yang Zhang*, Tao Li*. Solar Efficiency of Azo-Photoswitches for Energy Conversion: A Comprehensive Assessment. ChemSusChem 2023,16, e202300582.

23. Fanyi Min^†, Zhao-Yang Zhang^†, Zhiyuan Qu, Jie Gao, Xiaosong Shi, Haoran Long, Yixin Li, Shengnan Chen, Dongfang Dong, Yuanping Yi, Lang Jiang, Juehan Yang, Tao Li*, Yali Qiao*, Yanlin Song*. Humidity-Controlled Molecular Assembly and Photoisomerization Behavior with a Bubble-Assisted Patterning Approach. Small 2023,19, 2301362.

22. Si Wu^†, Zhao-Yang Zhang^†, Tao Li*, Ruzhu Wang*, Tingxian Li*. Optically-Controlled Variable-Temperature Storage and Upgrade of Thermal Energy by Photoswitchable Phase Change Materials. ACS Mater. Lett. 2023, 5, 2019–2027.

21. Tongtong Dang, Dongfang Dong, Jiabin Zhang, Yixin He, Zhao-Yang Zhang*, Tao Li*. Thiazolylazopyrazoles as Nonsymmetric Bis-Heteroaryl Azo Switches: High-Yield Visible-Light Photoisomerization and Increased Z-Isomer Stability by o-Carbonylation. Angew. Chem. Int. Ed. 2023, 62, e202301992.

20. Liang Fei^†, Zhao-Yang Zhang^†, Yongsong Tan, Ting Ye, Dongfang Dong, Yunjie Yin, Tao Li*, Chaoxia Wang*. Efficient and Robust Molecular Solar Thermal Fabric for Personal Thermal Management. Adv. Mater. 2023, 35, 2209768.

19. Haomiao Xu, Qinyuan Hong, Zhao-Yang Zhang, Xiangling Cai, Yurui Fan, Zhisong Liu, Wenjun Huang, Naiqiang Yan, Zan Qu*, Lizhi Zhang*. SO₂-Driven In Situ Formation of Superstable Hg₃Se₂Cl₂ for Effective Flue Gas Mercury Removal. Environ. Sci. Technol. 2023, 13, 5424–5432.

18. Mingchen Xie^†, Jia-Heng Cai^†, Guangyu Zhang, Sinyong Jung, Dongfang Dong, Zhao-Yang Zhang, Dong-Ying Zhou*, Liang-Sheng Liao, Tao Li*. Suppression and Utilization of Kasha's Rule: Realizing the Transformation from Blue to Near-Infrared Emission. Mater. Chem. Front. 2023, 7, 4092–4099.

17. Zhihang Wang, Zhenhua Wu, Zhiyu Hu*, Jessica Orrego-Hernández, Erzhen Mu, Zhao-Yang Zhang, Martyn Jevric, Yang Liu, Xuecheng Fu, Fengdan Wang, Tao Li*, Kasper Moth-Poulsen*. Chip-Scale Solar Thermal Electrical Power Generation. Cell Rep. Phys. Sci. 2022, 3, 100789.

16. Xianhui Huang^†, Zhichun Shangguan^†, Zhao-Yang Zhang, Chunyang Yu, Yixin He, Dong Fang, Wenjin Sun, Yan-Chun Li, Chenrui Yuan, Si Wu*, Tao Li*. Visible-Light-Induced Reversible Photochemical Crystal-Liquid Transitions of Azo-Switches for Smart and Robust Adhesives. Chem. Mater. 2022, 34, 2636–2644.

15. Zhichun Shangguan, Wenjin Sun, Zhao-Yang Zhang, Dong Fang, Zhihang Wang, Si Wu, Chao Deng, Xianhui Huang, Yixin He, Ruzhu Wang, Tingxian Li, Kasper Moth-Poulsen*, Tao Li*. A Rechargeable Molecular Solar Thermal System Below 0 ℃. Chem. Sci. 2022, 13, 6950–6958.

14. Zhihang Wang, Paul Erhart, Tao Li, Zhao-Yang Zhang, Diego Sampedro, Zhiyu Hu, Hermann A. Wegner, Olaf Brummel, Jörg Libuda, Mogens Brøndsted Nielsen, Kasper Moth-Poulsen*. Storing Energy with Molecular Photoisomers. Joule 2021, 5, 3116–3136. 

13. Si Wu, Tingxian Li*, Zhao-Yang Zhang, Tao Li, Ruzhu Wang*. Photoswitchable Phase Change Materials for Unconventional Thermal Energy Storage and Upgrade. Matter 2021, 4, 3385–3399. 

12. Dong Fang, Zhao-Yang Zhang*, Zhichun Shangguan, Yixin He, Chunyang Yu, Tao Li*. (Hetero)arylazo-1,2,3-triazoles: “Clicked” Photoswitches for Versatile Functionalization and Electronic Decoupling. J. Am. Chem. Soc. 2021, 143, 14502–14510. 

11. Yixin He, Zhichun Shangguan, Zhao-Yang Zhang*, Mingchen Xie, Chunyang Yu, Tao Li*. Azobispyrazole Family as Photoswitches Combining (Near-)Quantitative Bidirectional Isomerization and Widely Tunable Thermal Half-lives from Hours to Years. Angew. Chem. Int. Ed. 2021, 60, 16539–16546. 

10. Zhao-Yang Zhang, Yixin He, Zhihang Wang, Jiale Xu, Mingchen Xie, Peng Tao, Deyang Ji, Kasper Moth-Poulsen*, Tao Li*. Photochemical Phase Transitions Enable Coharvesting of Photo Energy and Ambient Heat for Energetic Molecular Solar Thermal Batteries That Upgrade Thermal Energy. J. Am. Chem. Soc. 2020, 142, 12256–12264. 

9. Ying Zhou, Zhao-Yang Zhang*, Xianhui Huang, Jiantong Li, Tao Li*. Versatile Functionalization of Carbon Nanomaterials by Ferrate (VI). Nano-Micro Lett. 2020, 12, 32. 

8. Zhao-Yang Zhang, Yixin He, Ying Zhou, Chunyang Yu*, Lu Han, Tao Li*. Pyrazolylazophenyl Ether Based Photoswitches: Facile Synthesis, (Near-)Quantitative Photoconversion, Long Thermal Half-Life, Easy Functionalization and Versatile Applications in Light-Responsive Systems. Chem. Eur. J. 2019, 25, 13402–13410. 

7. Deyang Ji, Tao Li*, Jie Liu, Saeed Amirjalayer, Mianzeng Zhong, Zhao-Yang Zhang, Xianhui Huang, Zhongming Wei, Huanli Dong, Wenping Hu*, Harald Fuchs*. Band-like Transport in Small-Molecule Thin Films toward High Mobility and Ultrahigh Detectivity Phototransistor Arrays. Nat. Commun. 2019, 10, 12. 

6. Qing Wang, Liang Ma, Zhonghua Liu, Xu Zhang, Zhao-Yang Zhang, Zhichun Shangguan, Xianhui Huang, Yuqing Liu, Jingtao Lv*, Haiming Zhang, Lifeng Chi, Tao Li*. Triazatriangulene Platform for Self-assembled Monolayers of Free-standing Diarylethene. Sci. China Mater. 2018, 61, 1345–1350. 

5. Zhao-Yang Zhang, Deyang Ji, Wenting Mao, Yu Cui, Qing Wang, Lu Han, Hongliang Zhong, Zhongming Wei, Yixin Zhao, Kasper Nørgaard, Tao Li*. Dry Chemistry of Ferrate(VI): A Solvent-free Mechanochemical Way for Versatile Green Oxidation. Angew. Chem. Int. Ed. 2018, 57, 10949–10953. 

4. Deyang Ji, Tao Li*, Ye Zou, Ming Chu, Ke Zhou, Jinyu Liu, Guofeng Tian, Zhao-Yang Zhang, Xu Zhang, Liqiang Li, Dezhen Wu, Huanli Dong, Qian Miao, Harald Fuchs*, Wenping Hu*. Copolymer Dielectrics with Balanced Chain-packing Density and Surface Polarity for High-performance Flexible Organic Electronics. Nat. Commun. 2018, 9, 2339. 

3. Zhao-Yang Zhang, Tao Li*. Single-Chain and Monolayered Conjugated polymers for Molecular Electronics. Chin. Chem. Lett. 2016, 27, 1209–1222. 

2. Zhao-Yang Zhang, Xue-Cheng Xu*. Nondestructive Covalent Functionalization of Carbon Nanotubes by Selective Oxidation of the Original Defects with K₂FeO₄. Appl. Surf. Sci. 2015, 346, 520–527.

1. Zhao-Yang Zhang, Xue-Cheng Xu*. Wrapping Carbon Nanotubes with Poly(sodium 4-styrenesulfonate) for Enhanced Adsorption of Methylene Blue and Its Mechanism. Chem. Eng. J. 2014, 256, 85–92.

科研项目：

1. 功能晶态材料化学江西省重点实验室开放基金，一般项目，2024SSY05161，2024−2026，主持

2. 国家自然科学基金，青年科学基金项目，22209110，2023−2025，主持

3. 杭州苏博科凌科技有限公司，技术开发合同，2023−2024，主持

4. 中国博士后科学基金会第68批面上资助，2020M681279，2021−2022，主持

5. 上海市博士后日常经费资助，2020−2022，主持

6. 上海市教委，老员工创新活动计划资助项目，B-8906-09-0115，2010−2011，主持

发明专利：

[1] 李涛，张召阳，上官之春，黄先会。一种基于吡唑基偶氮苯胺的光控小分子粘合剂，ZL 202111181519.0

[2] 李涛，张召阳，贺逸昕，周颖。一种吡唑基偶氮苯酚化合物及其合成、衍生，ZL 201811257615.7

[3] 李涛，张召阳，王晴。一种制备功能化碳材料的方法，ZL 201610659324.5

[4] Tao Li, Zhaoyang Zhang, Ying Zhou. Method for preparing functionalized carbon materials, US10913657B2

个人简介 

张召阳，1990年出生，河南南阳人。现为3044am永利集团副教授。2020年6月博士毕业于上海交通大学并留校进行博士后研究（导师为李涛教授）；2023年9月至2024年9月在上海交通大学任助理研究员（专职科研岗）；2024年9月加入3044am永利集团，任副教授、硕士生导师。主要从事功能分子材料的研究，在光开关分子的设计合成、性质调控与储能应用上取得了一系列有国际影响的成果。共发表SCI论文30篇，其中以第一作者或通讯作者身份在J. Am. Chem. Soc. (3篇)，Angew. Chem. Int. Ed. (5篇)和Adv. Mater.等国际重要期刊上发表论文18篇，论文总被引用1000多次。科研工作得到了国家自然科学基金青年项目、中国博士后科学基金、上海市博士后日常经费资助和横向项目等的支持。受邀担任Angew. Chem. Int. Ed.期刊的审稿人。

ORCID链接：https://orcid.org/0000-0003-0991-9489

本课题组隶属绿色有机合成与催化研究团队，团队负责人为邓国军教授（副董事长）。

绿色有机合成与催化研究团队每年可招收多名博士研究生和硕士研究生，欢迎科研兴趣浓厚、踏实上进的员工踊跃报考！

同时欢迎本科生加入本课题组开展长期科研训练！

有意向的员工可直接联系zy_zhang@xtu.edu.cn